  {"id":485202,"date":"2021-07-30T14:46:30","date_gmt":"2021-07-30T18:46:30","guid":{"rendered":"https:\/\/www.rochester.edu\/newscenter\/?p=485202"},"modified":"2021-08-13T16:06:11","modified_gmt":"2021-08-13T20:06:11","slug":"pulsed-laser-in-liquids-technique-identifies-effective-catalysts-485202","status":"publish","type":"post","link":"https:\/\/www.rochester.edu\/newscenter\/pulsed-laser-in-liquids-technique-identifies-effective-catalysts-485202\/","title":{"rendered":"Pulsed lasers in liquids speed up the hunt for effective catalysts"},"content":{"rendered":"<h2 style=\"width: 85%; font-weight: bold; line-height: 135%; margin-bottom: 0.5em;\">Rochester researchers have documented the pulsed-laser-in-liquid technique\u2019s multiple advantages over traditional wet lab methods.<\/h2>\n<p>Chemical catalysts are the change agents behind the production of just about everything we use in our daily lives, from plastics to prescription drugs. When the right catalysts are mixed with the right chemical compounds, molecules that would otherwise take years to interact do so in mere seconds.<\/p>\n<p>However, developing even one catalyst material to trigger this precise choreography of atoms can take months, even years, when using traditional wet chemistry procedures that use only chemical reactions, often in the liquid phase, to grow nanoparticles.<\/p>\n<p>Ä¢¹½´«Ã½ researchers say there is a way to shorten that process dramatically\u2014by instead using pulsed lasers in liquids to quickly create carefully tuned, systematic arrays of nanoparticles that can be easily compared and tested for use as catalysts.<\/p>\n<p>The process is described in a <a href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.chemrev.0c01069\"><em>Chemical Reviews<\/em> article<\/a> by <a href=\"http:\/\/hajim.rochester.edu\/che\/people\/faculty\/mueller-astrid\/index.html\">Astrid M\u00fcller<\/a>, an assistant professor of <a href=\"http:\/\/hajim.rochester.edu\/che\/\">chemical engineering<\/a> at the <a href=\"https:\/\/rochester.edu\">Ä¢¹½´«Ã½<\/a> who has adapted the technique for her work on sustainable energy solutions. Three PhD students in her lab\u2014coauthors Ryland Forsythe, Connor Cox, and Madeleine Wilsey\u2014conducted an exhaustive review of almost 600 previous papers involving the use of pulsed lasers in liquids. As a result, their article is the most comprehensive, up-to-date survey of a technology that was first developed in 1987.<\/p>\n<div class=\"embed-container\"><iframe loading=\"lazy\" title=\"YouTube video player\" src=\"https:\/\/www.youtube.com\/embed\/O8VSmaGavUs\" width=\"560\" height=\"315\" frameborder=\"0\" allowfullscreen=\"allowfullscreen\"><span data-mce-type=\"bookmark\" style=\"display: inline-block; width: 0px; overflow: hidden; line-height: 0;\" class=\"mce_SELRES_start\">\ufeff<\/span><\/iframe><\/div>\n<p>&nbsp;<\/p>\n<h3><\/h3>\n<h3><strong>Pulsed lasers in liquids an\u00a0<\/strong><strong>\u2018indispensable tool\u2019 for\u00a0<\/strong><b>discovering catalysts<\/b><\/h3>\n<p>So how does pulsed-laser-in-liquid synthesis work?<\/p>\n<ul>\n<li>A pulsed laser is directed at a solid material immersed in liquid. This creates a high-temperature, high-pressure plasma near the surface of the solid.<\/li>\n<li>As the plasma decays, it vaporizes molecules in the surrounding liquid, leading to a cavitation bubble. Within the bubble, chemical reactions begin to occur between particles from the liquid and particles that were ablated, or knocked loose, from the solid.<\/li>\n<li>After periodic expansions and contractions, the cavitation bubble violently implodes, causing shock waves and rapid cooling. Nanoparticles from the bubble condense in small clusters that are injected into the surrounding liquid and become stable.<\/li>\n<\/ul>\n<figure id=\"attachment_484792\" aria-describedby=\"caption-attachment-484792\" style=\"width: 1000px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-484792\" src=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/06\/fea-pulsed-lasers-liquid.jpg\" alt=\"Illustration of a green pulsed laser beam striking a yellow solid immersed in a blue liquid to create uniform purple and blue nanoparticles.\" width=\"1000\" height=\"600\" srcset=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/06\/fea-pulsed-lasers-liquid.jpg 1000w, https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/06\/fea-pulsed-lasers-liquid-630x378.jpg 630w, https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/06\/fea-pulsed-lasers-liquid-193x117.jpg 193w, https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/06\/fea-pulsed-lasers-liquid-768x461.jpg 768w\" sizes=\"auto, (max-width: 1000px) 100vw, 1000px\" \/><figcaption id=\"caption-attachment-484792\" class=\"wp-caption-text\">A pulsed laser beam (green) strikes a solid immersed in liquid, triggering a sequence of events that create uniform nanoparticles with controlled properties. (Illustration courtesy of Astrid M\u00fcller)<\/figcaption><\/figure>\n<p>The pulsed-laser-in-liquids technique offers multiple advantages over traditional wet-lab synthesis of nanomaterials. According to M\u00fcller:<\/p>\n<ul>\n<li>Because the reactions are confined primarily within the cavitation bubble, the resulting nanoparticles have remarkably uniform properties. \u201cEvery particle that is made is created under the same conditions,\u201d she says.<\/li>\n<li>The properties of the nanoparticles can be easily fine-tuned by adjusting the laser pulses and the chemical compositions of the solid and surrounding fluid.<\/li>\n<li>Laser-made nanocatalysts are intrinsically more active than those obtained by wet chemistry methods.<br \/>\nMetastable nanomaterials with non-equilibrium structures and compositions can easily be produced. Such materials cannot be made under moderate temperatures and pressures.<\/li>\n<li>Laser synthesis can be controlled remotely, increasing the potential for large-scale industrial applications.<\/li>\n<li>Pulsed-laser-in-liquids synthesis of nanomaterials is also far more rapid than traditional methods. The technique can prepare bulk quantities of a nanoparticle in an hour or less. Systematic arrays of 70 materials can be made in a week.<\/li>\n<\/ul>\n<figure id=\"attachment_486932\" aria-describedby=\"caption-attachment-486932\" style=\"width: 1000px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-486932\" src=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/07\/pulsed-lasers-fasusi.jpg\" alt=\"student lit by a red glow working in a lab\" width=\"1000\" height=\"667\" srcset=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/07\/pulsed-lasers-fasusi.jpg 1000w, https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/07\/pulsed-lasers-fasusi-630x420.jpg 630w, https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/07\/pulsed-lasers-fasusi-768x512.jpg 768w\" sizes=\"auto, (max-width: 1000px) 100vw, 1000px\" \/><figcaption id=\"caption-attachment-486932\" class=\"wp-caption-text\">Eisenberg Summer Research Fellow Omolade Fasusi, a rising senior studying chemical engineering at Rochester, dries a metal nanoparticle-loaded carbon fiber paper electrode for electrocatalysis experiments. (Ä¢¹½´«Ã½ photo \/ J. Adam Fenster)<\/figcaption><\/figure>\n<p>\u201cThese advantages make this an indispensable as a tool for discovery,\u201d says M\u00fcller, whose background includes work in lasers, materials, and electrocatalysis. \u201cYou often have people who know lasers and materials, or maybe electrocatalysis and materials, but you very rarely get someone with expertise in all three.\u201d<\/p>\n<p>She says, \u201cThis is what compelled us to write this paper, because the M\u00fcller group can bring together the perspectives of all three fields.\u201d<\/p>\n<h3><strong>How catalysts can combat climate change<\/strong><\/h3>\n<p>While working as a staff scientist at Caltech, M\u00fcller pioneered an adaption of the laser-in-liquids technique to prepare nonprecious water-splitting electrocatalysts that liberate oxygen from water to produce clean hydrogen. At Rochester, the M\u00fcller group expands on her expertise to study laser-made electrocatalysts as a way to turn climate-damaging carbon dioxide (CO2) into a closed cycle of useful liquid fuels, such as methanol or ethanol.<\/p>\n<p>\u201cIf you were to burn these fuels again, you make CO2 again, so you go round and round. The carbon always stays within the cycle, and does not contribute to more climate change,\u201d M\u00fcller says. \u201cFor that to work we need catalysts, and no one knows yet what those catalysts would be\u2014what would work and why, and why other catalysts don\u2019t work.\u201d<\/p>\n<p>Hence her interest in using pulsed-laser-in-liquid synthesis to accelerate the process. \u201cIt is hugely important because we can\u2019t just sit and hope for the best with climate change; we need to work on successor technologies now,\u201d she says.<\/p>\n<figure id=\"attachment_487032\" aria-describedby=\"caption-attachment-487032\" style=\"width: 1000px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-487032\" src=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/07\/pulsed-lasers-green.jpg\" alt=\"glowing green item inside a container\" width=\"1000\" height=\"667\" srcset=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/07\/pulsed-lasers-green.jpg 1000w, https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/07\/pulsed-lasers-green-630x420.jpg 630w, https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/07\/pulsed-lasers-green-768x512.jpg 768w\" sizes=\"auto, (max-width: 1000px) 100vw, 1000px\" \/><figcaption id=\"caption-attachment-487032\" class=\"wp-caption-text\">A new technique studied in Astrid M\u00fcller&#8217;s lab\u00a0involves shooting pulsed lasers at a solid immersed in liquid to create nanoparticles with remarkably controlled properties. (Ä¢¹½´«Ã½ photo \/ J. Adam Fenster)<\/figcaption><\/figure>\n<p>So far, pulsed-laser-in-liquid synthesis has had only limited commercial use. The start-up cost of investing in laser technology is a stumbling block for many companies, M\u00fcller says. \u201cBut that will change as this method gets more and more traction,\u201d she believes.<\/p>\n<p>Thanks to M\u00fcller\u2019s lab, pulsed-laser-in-liquids synthesis is certainly getting more attention. Within three weeks, their paper had become a catalyst of its own by being downloaded more than 1,500 times.<\/p>\n<hr \/>\n<h3><strong>Read more<\/strong><\/h3>\n<div class=\"large-up-3\">\n<div class=\"column\" style=\"padding-left: 0px;\"><a href=\"https:\/\/www.rochester.edu\/newscenter\/novel-chirped-pulses-defy-conventional-wisdom-484312\/\"><img decoding=\"async\" style=\"margin-bottom: 10px;\" src=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2021\/06\/fea-novel-chirped-pulses.jpg\" alt=\"illustration of the optical fiber Kerr resonator with rainbow pattern in foreground.\" \/><strong>Novel chirped pulses defy \u2018conventional wisdom\u2019<\/strong><\/a><br \/>\n<span style=\"font-size: .9em;\">Rochester researchers have advanced a groundbreaking technique first pioneered at the University\u2019s Laboratory for Laser Energetics to produce chirped pulses with relatively low-quality, inexpensive equipment.<\/span><\/div>\n<div class=\"column\" style=\"padding-left: 0px;\"><a href=\"https:\/\/www.rochester.edu\/newscenter\/lasers-etch-a-perfect-solar-energy-absorber-414902\/\"><img decoding=\"async\" style=\"margin-bottom: 10px;\" src=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2020\/02\/fea-solar-energy-absorber.jpg\" alt=\"etched metal surface on a blue surface with one red and one black wire attached at the right side.\" \/><strong>Lasers etch a \u2018perfect\u2019 solar energy absorber<\/strong><\/a><br \/>\n<span style=\"font-size: .9em;\">The Ä¢¹½´«Ã½ research lab that recently used lasers to create unsinkable metal structures has now demonstrated how the same technology could be used to create highly efficient solar power generators.<\/span><\/div>\n<div class=\"column\" style=\"padding-left: 0px;\"><a href=\"https:\/\/www.rochester.edu\/newscenter\/rochesters-breakthrough-in-laser-science-earns-nobel-prize-340302\/\"><img decoding=\"async\" style=\"margin-bottom: 10px;\" src=\"https:\/\/www.rochester.edu\/newscenter\/wp-content\/uploads\/2018\/10\/fea-mourou-strickland.jpg\" alt=\"two archival photos of G\u00e9rard Mourou and Donna Strickland.\" \/><strong>Rochester breakthrough in laser science earns Nobel Prize<\/strong><\/a><br \/>\n<span style=\"font-size: .9em;\">Ä¢¹½´«Ã½ graduate Donna Strickland \u201989 (PhD) and former optics faculty member G\u00e9rard Mourou shared the 2018 Nobel Prize in Physics for work they undertook at the Laboratory for Laser Energetics.<\/span><\/div>\n<\/div>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>In the most comprehensive, up-to-date survey of a technology that was first developed in 1987, Rochester researchers have documented the advantages of using the pulsed-laser-in-liquids technique over traditional wet laboratory methods.<\/p>\n","protected":false},"author":286,"featured_media":486922,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[116],"tags":[18842,29502,18632,18572],"class_list":["post-485202","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-sci-tech","tag-department-of-chemical-and-sustainability-engineering","tag-featured-post-side","tag-hajim-school-of-engineering-and-applied-sciences","tag-research-finding"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.5 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Pulsed lasers in liquids speed up the hunt for effective catalysts<\/title>\n<meta name=\"description\" content=\"Ä¢¹½´«Ã½ researchers have documented the benefits of the pulsed-laser-in-liquids technique over traditional wet lab methods.\" \/>\n<meta name=\"robots\" content=\"index, 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